We provide a primal-dual framework for randomized approximation algorithms utilizing semidefinite programming (SDP) relaxations. Our framework pairs a continuum of APX-complete problems including MaxCut, Max2Sat, MaxDicut, and more generally, Max-Boolean Constraint Satisfaction and MaxQ (maximization of a positive semidefinite quadratic form over the hypercube) with new APX-complete problems which are stated as convex optimization problems with exponentially many variables. These new dual counterparts, based on what we call Grothendieck covers, range from fractional cut covering problems (for MaxCut) to tensor sign covering problems (for MaxQ). For each of these problem pairs, our framework transforms the randomized approximation algorithms with the best known approximation factors for the primal problems to randomized approximation algorithms for their dual counterparts with reciprocal approximation factors which are tight with respect to the Unique Games Conjecture. For each APX-complete pair, our algorithms solve a single SDP relaxation and generate feasible solutions for both problems which also provide approximate optimality certificates for each other. Our work utilizes techniques from areas of randomized approximation algorithms, convex optimization, spectral sparsification, as well as Chernoff-type concentration results for random matrices.