Recent advances in Large Reasoning Models have significantly improved chain-of-thought (CoT) capabilities via reinforcement learning (RL). However, generated reasoning chains frequently suffer from structural redundancy (i.e., \emph{overthinking}), incurring high computational overhead without improving answer correctness. Existing mitigation strategies typically rely on token-uniform length penalties, which provide coarse, segment-agnostic pressure toward shorter outputs and can inadvertently suppress useful reasoning alongside redundancy. To address this, we demonstrate that inefficiency concentrates in high-probability segments with low marginal utility. We derive a theoretical characterization of segment suboptimality under the correctness-length trade-off objective and propose \textsc{SLAT} (Segment-Level Adaptive Trimming), an RL framework that selectively suppresses redundant segments based on this criterion. Empirical results on standard benchmarks indicate that \textsc{SLAT} establishes a superior accuracy-efficiency Pareto frontier, reducing reasoning length by $50\%$ relative to uncompressed baselines while maintaining competitive accuracy. Overall, our results suggest that theoretically grounded, segment-aware trimming is a promising direction for efficient CoT reasoning in large language models.