Recent advances in Text-To-Speech (TTS) synthesis have achieved near-human speech quality in neutral speaking styles. However, most existing approaches either depend on costly emotion annotations or optimize surrogate objectives that fail to adequately capture perceptual emotional quality. As a result, the generated speech, while semantically accurate, often lacks expressive and emotionally rich characteristics. To address these limitations, we propose RLAIF-SPA, a novel framework that integrates Reinforcement Learning from AI Feedback (RLAIF) to directly optimize both emotional expressiveness and intelligibility without human supervision. Specifically, RLAIF-SPA incorporates Automatic Speech Recognition (ASR) to provide semantic accuracy feedback, while leveraging structured reward modeling to evaluate prosodic-emotional consistency. RLAIF-SPA enables more precise and nuanced control over expressive speech generation along four structured evaluation dimensions: Structure, Emotion, Speed, and Tone. Extensive experiments on Libri-Speech, MELD, and Mandarin ESD datasets demonstrate consistent gains across clean read speech, conversational dialogue, and emotional speech. On Libri-Speech, RLAIF-SPA consistently outperforms Chat-TTS, achieving a 26.1% reduction in word error rate, a 9.1% improvement in SIM-O, and over 10% gains in human subjective evaluations.