This paper introduces to a structured application of the One-Class approach and the One-Class-One-Network model for supervised classification tasks, specifically addressing a vowel phonemes classification case study within the Automatic Speech Recognition research field. Through pseudo-Neural Architecture Search and Hyper-Parameters Tuning experiments conducted with an informed grid-search methodology, we achieve classification accuracy comparable to nowadays complex architectures (90.0 - 93.7%). Despite its simplicity, our model prioritizes generalization of language context and distributed applicability, supported by relevant statistical and performance metrics. The experiments code is openly available at our GitHub.