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首先，請先把你的 ButtonField 轉換成 TemplateField，把它改成如下的樣子：

<Columns>
    <asp:TemplateField ShowHeader="False">
        <ItemTemplate>
            <asp:Button ID="Button1" runat="server" CausesValidation="false" CommandName="Details"
                CommandArgument='<%# Eval("OrderID") %>' Text="Details" />
        </ItemTemplate>
    </asp:TemplateField>
    <asp:BoundField DataField="OrderID" HeaderText="OrderID" ReadOnly="True" SortExpression="OrderID" />
    <asp:BoundField DataField="CustomerID" HeaderText="CustomerID" SortExpression="CustomerID" />
    <asp:BoundField DataField="EmployeeID" HeaderText="EmployeeID" SortExpression="EmployeeID" />
    <asp:BoundField DataField="ShipName" HeaderText="ShipName" SortExpression="ShipName" />
    ...
</Columns>

注意 CommandArgument='<%# Eval("OrderID") %>' 這句必須手動加上去。把 OrderID 改名成你的欄位名稱。

接著，請修改 GridView1_RowCommand() 如下：

    Protected Sub GridView1_RowCommand(...) Handles GridView1.RowCommand
        If e.CommandName = "Details" Then
            Response.Redirect(String.Format("Default.aspx?ID={0}", e.CommandArgument))
        End If
    End Sub