This paper addresses the problem of decentralized spectrum sharing in vehicle-to-everything (V2X) communication networks. The aim is to provide resource-efficient coexistence of vehicle-to-infrastructure(V2I) and vehicle-to-vehicle(V2V) links. A recent work on the topic proposes a multi-agent reinforcement learning (MARL) approach based on deep Q-learning, which leverages a fingerprint-based deep Q-network (DQN) architecture. This work considers an extension of this framework by combining Double Q-learning (via Double DQN) and transfer learning. The motivation behind is that Double Q-learning can alleviate the problem of overestimation of the action values present in conventional Q-learning, while transfer learning can leverage knowledge acquired by an expert model to accelerate learning in the MARL setting. The proposed algorithm is evaluated in a realistic V2X setting, with synthetic data generated based on a geometry-based propagation model that incorporates location-specific geographical descriptors of the simulated environment(outlines of buildings, foliage, and vehicles). The advantages of the proposed approach are demonstrated via numerical simulations.