Computing accessible information for an ensemble of quantum states is a basic problem in quantum information theory. We show that the recently obtained optimality criterion (A.S. Holevo, Lobachevskii J. Math., \textbf{43}:7 (2022), 1646-1650), when applied to specific ensembles of states leads to nontrivial tight entropy inequalities that are discrete relatives of the famous log-Sobolev inequality. In this light, the hypothesis of globally information-optimal measurement for an ensemble of equiangular equiprobable states (quantum pyramids) (B.-G. Englert and J. Řeháček, J. Mod. Optics \textbf{57 }N3 (2010) 218-226) is reconsidered and the corresponding entropy inequalities are proposed. Via the optimality criterion, this suggests also an approach to the proof of the conjectures concerning globally information-optimal observables for quantum pyramids.