Sea surface temperature (SST) is a fundamental physical parameter characterising the thermal state of sea surface. Due to the intricate thermal interactions between land, sea, and atmosphere, the spatial gradients of SST in coastal waters often appear at finer spatial scales than those in open ocean waters. The Thermal Infrared Sensor (TIRS) onboard Landsat-8, with its 100-meter spatial resolution, offers a unique opportunity to uncover fine-scale coastal SST patterns that would otherwise be overlooked by coarser-resolution thermal sensors. In this study, we first analysed the spatiotemporal patterns of SST in South Australia's temperate coastal waters from 2014 to 2023 by developing an operational approach for SST retrieval from the Landsat-8 TIRS sensor. A buoy was deployed off the coast of Port Lincoln, South Australia, to validate the quality of SST retrievals. Then the daily baseline climatology of SST with 100 m resolution was constructed, which allowed for the detection and analysis of anomalous SST events. Our results suggest the following: (1) the satellite-derived SST data aligned well with the in-situ measured SST values; (2) the semi-enclosed, shallow regions of Upper Spencer Gulf and Upper St Vincent Gulf showed higher temperatures during summer and cooler temperatures during winter than waters closer to the open ocean, resulting in a higher seasonal variation in SST; (3) the near-shore shallow areas in Spencer Gulf and St Vincent Gulf, and regions surrounding Kangaroo Island, were identified to have a higher probability of SST anomalies compared to the rest of the study area; and (4) anomalous SST events were more likely to happen during the warm months than the cool months. We hope these findings would be helpful in supporting the fishing and aquaculture industries in the coastal waters of South Australia.