Stationary subspace analysis (SSA) searches for linear combinations of the components of nonstationary vector time series that are stationary. These linear combinations and their number defne an associated stationary subspace and its dimension. SSA is studied here for zero mean nonstationary covariance processes. We characterize stationary subspaces and their dimensions in terms of eigenvalues and eigenvectors of certain symmetric matrices. This characterization is then used to derive formal statistical tests for estimating dimensions of stationary subspaces. Eigenstructure-based techniques are also proposed to estimate stationary subspaces, without relying on previously used computationally intensive optimization-based methods. Finally, the introduced methodologies are examined on simulated and real data.