Sufficient conditions are provided under which the log-likelihood ratio test statistic fails to have a limiting chi-squared distribution under the null hypothesis when testing between one and two components under a general two-component mixture model, but rather tends to infinity in probability. These conditions are verified when the component densities describe continuous-time, discrete-statespace Markov chains and the results are illustrated via a parametric bootstrap simulation on an analysis of the migrations over time of a set of corporate bonds ratings. The precise limiting distribution is derived in a simple case with two states, one of which is absorbing which leads to a right-censored exponential scale mixture model. In that case, when centred by a function growing logarithmically in the sample size, the statistic has a limiting distribution of Gumbel extreme-value type rather than chi-squared.