The Carathéodory's Extension Theorem is a powerful tool that allows us to generate a measure, over a sigma-algebra, from a pre-measure defined over an algebra of sets. However, although this result reduces our work to define a measure by only needing to define a pre-measure, it is not always easy to define the latter. The problem occurs when taking the smallest algebra that contains a family of targeted sets, it can be very complicated to consistently define the value of the pre-measure over its finite union of these sets - a union that is an element of the algebra. Thus, our objective in this article is to reproduce an extension theorem, just like the Carathéodory's Extension Theorem, but in the context of probability measures and replacing the need for a probability pre-measure defined over an algebra for now a quasi-measure defined over a refinement. The gain, then, is that the \textit{manual elaboration} of a quasi-measure is simpler than the elaboration of a pre-measure, since a refinement is a simpler structure than an algebra.