We derive novel results on the ergodic theory of irreducible, aperiodic Markov chains. We show how to optimally steer the network flow to a stationary distribution over a finite or infinite time horizon. Optimality is with respect to an entropic distance between distributions on feasible paths. When the prior is reversible, it shown that solutions to this discrete time and space steering problem are reversible as well. A notion of temperature is defined for Boltzmann distributions on networks, and problems analogous to cooling (in this case, for evolutions in discrete space and time) are discussed.