Polygonal collision avoidance (PCA) is short for the problem of collision avoidance between two polygons (i.e., polytopes in planar) that own their dynamic equations. This problem suffers the inherent difficulty in dealing with non-smooth boundaries and recently optimization-defined metrics, such as signed distance field (SDF) and its variants, have been proposed as control barrier functions (CBFs) to tackle PCA problems. In contrast, we propose an optimization-free smooth CBF method in this paper, which is computationally efficient and proved to be nonconservative. It is achieved by three main steps: a lower bound of SDF is expressed as a nested Boolean logic composition first, then its smooth approximation is established by applying the latest log-sum-exp method, after which a specified CBF-based safety filter is proposed to address this class of problems. To illustrate its wide applications, the optimization-free smooth CBF method is extended to solve distributed collision avoidance of two underactuated nonholonomic vehicles and drive an underactuated container crane to avoid a moving obstacle respectively, for which numerical simulations are also performed.