The ability to perform aggressive movements, which are called aggressive flights, is important for quadrotors during navigation. However, aggressive quadrotor flights are still a great challenge to practical applications. The existing solutions to aggressive flights heavily rely on a predefined trajectory, which is a time-consuming preprocessing step. To avoid such path planning, we propose a curiosity-driven reinforcement learning method for aggressive flight missions and a similarity-based curiosity module is introduced to speed up the training procedure. A branch structure exploration (BSE) strategy is also applied to guarantee the robustness of the policy and to ensure the policy trained in simulations can be performed in real-world experiments directly. The experimental results in simulations demonstrate that our reinforcement learning algorithm performs well in aggressive flight tasks, speeds up the convergence process and improves the robustness of the policy. Besides, our algorithm shows a satisfactory simulated to real transferability and performs well in real-world experiments.