As blockchain technology gains traction for enhancing data security and operational efficiency, traditional centralized authentication systems remain a significant bottleneck. This paper addresses the challenge of integrating decentralized authentication and access control within distributed networks. We propose a novel solution named ChainGuard, a fully decentralized authentication and access control mechanism based on smart contracts. ChainGuard eliminates the need for a central server by leveraging blockchain technology to manage user roles and permissions dynamically. Our scheme supports user interactions across multiple organizations simultaneously, enhancing security, efficiency, and transparency. By addressing key challenges such as scalability, security, and transparency, ChainGuard not only bridges the gap between traditional centralized systems and blockchain's decentralized ethos but also enhances data protection and operational efficiency.