In this paper, we leverage the advantages of event cameras to resist harsh lighting conditions, reduce background interference, achieve high time resolution, and protect facial information to study the long-sequence event-based person re-identification (Re-ID) task. To this end, we propose a simple and efficient long-sequence event Re-ID model, namely the Spike-guided Spatiotemporal Semantic Coupling and Expansion Network (S3CE-Net). To better handle asynchronous event data, we build S3CE-Net based on spiking neural networks (SNNs). The S3CE-Net incorporates the Spike-guided Spatial-temporal Attention Mechanism (SSAM) and the Spatiotemporal Feature Sampling Strategy (STFS). The SSAM is designed to carry out semantic interaction and association in both spatial and temporal dimensions, leveraging the capabilities of SNNs. The STFS involves sampling spatial feature subsequences and temporal feature subsequences from the spatiotemporal dimensions, driving the Re-ID model to perceive broader and more robust effective semantics. Notably, the STFS introduces no additional parameters and is only utilized during the training stage. Therefore, S3CE-Net is a low-parameter and high-efficiency model for long-sequence event-based person Re-ID. Extensive experiments have verified that our S3CE-Net achieves outstanding performance on many mainstream long-sequence event-based person Re-ID datasets. Code is available at:https://github.com/Mhsunshine/SC3E_Net.