This is the preprint version of the article published in IEEE Access vol. 13, pp. 146503--146526, 2025, doi:10.1109/ACCESS.2025.3599541. Please cite the published version. Urban air pollution remains a pressing global concern, particularly in densely populated and traffic-intensive metropolitan areas like Delhi, where exposure to harmful pollutants severely impacts public health. Delhi, being one of the most polluted cities globally, experiences chronic air quality issues due to vehicular emissions, industrial activities, and construction dust, which exacerbate its already fragile atmospheric conditions. Traditional pollution mitigation strategies, such as static air purifying installations, often fail to maximize their impact due to suboptimal placement and limited adaptability to dynamic urban environments. This study presents a novel deep reinforcement learning (DRL) framework to optimize the placement of air purification booths to improve the air quality index (AQI) in the city of Delhi. We employ Proximal Policy Optimization (PPO), a state-of-the-art reinforcement learning algorithm, to iteratively learn and identify high-impact locations based on multiple spatial and environmental factors, including population density, traffic patterns, industrial influence, and green space constraints. Our approach is benchmarked against conventional placement strategies, including random and greedy AQI-based methods, using multi-dimensional performance evaluation metrics such as AQI improvement, spatial coverage, population and traffic impact, and spatial entropy.