Zero-Shot Composed Image Retrieval (ZS-CIR) aims to retrieve a target image based on a query composed of a reference image and a relative caption without training samples. Existing ZS-CIR datasets often suffer from complete irrelevance between reference and target images due to noisy image sources, and do not achieve a true zero-shot scenario as they use public image datasets that models like CLIP have been trained on. To tackle these challenges, we introduce ZeroSight, a novel benchmark for ZS-CIR. It includes a dataset with consistent reference-target pairs sourced from videos, a data construction pipeline, and evaluation methods that consider the ranking of multiple positive and negative target images. We ensure visually and semantically consistent reference-target pairs by extracting frames from a single video and generating relative captions using LLM-assisted methods. To ensure a true zero-shot scenario, we use video data published after March 31, 2022, ensuring it was not included in CLIP's pre-training data. Additionally, we propose a training-free MLLM-driven method, SC4CIR (Symmetric Consistency for CIR), which can effectively identify hard negative targets through 3 symmetric consistency checks. This method is plug-and-play, seamlessly integrating with various CIR methods and significantly improving performance. Our experimental results from 27 methods reveal that current ZS-CIR datasets and evaluation metrics result in inflated retrieval performance, exaggerating the capabilities of CIR methods. Our benchmark and models can be accessed at https://github.com/sotayang/ZeroSight.