Biomedical Named Entity Recognition (BioNER), task6 in BioASQ (A challenge in large-scale biomedical semantic indexing and question answering), is crucial for extracting information from scientific literature but faces hurdles such as distinguishing between similar entity types like genes and chemicals. This study evaluates the GLiNER-BioMed model on a BioASQ dataset and introduces a targeted dictionary-based post-processing strategy to address common misclassifications. While this post-processing approach demonstrated notable improvement on our development set, increasing the micro F1-score from a baseline of 0.79 to 0.83, this enhancement did not generalize to the blind test set, where the post-processed model achieved a micro F1-score of 0.77 compared to the baselines 0.79. We also discuss insights gained from exploring alternative methodologies, including Conditional Random Fields. This work highlights the potential of dictionary-based refinement for pre-trained BioNER models but underscores the critical challenge of overfitting to development data and the necessity of ensuring robust generalization for real-world applicability.