While Ukrainian NLP has seen progress in many texts processing tasks, emotion classification remains an underexplored area with no publicly available benchmark to date. In this work, we introduce EmoBench-UA, the first annotated dataset for emotion detection in Ukrainian texts. Our annotation schema is adapted from the previous English-centric works on emotion detection (Mohammad et al., 2018; Mohammad, 2022) guidelines. The dataset was created through crowdsourcing using the Toloka.ai platform ensuring high-quality of the annotation process. Then, we evaluate a range of approaches on the collected dataset, starting from linguistic-based baselines, synthetic data translated from English, to large language models (LLMs). Our findings highlight the challenges of emotion classification in non-mainstream languages like Ukrainian and emphasize the need for further development of Ukrainian-specific models and training resources.