Modern software development demands code that is maintainable, testable, and scalable by organizing the implementation into modular components with iterative reuse of existing codes. We formalize this iterative, multi-turn paradigm as codeflow and introduce CodeFlowBench, the first benchmark designed to comprehensively evaluate LLMs' ability to perform codeflow - implementing new functionality by reusing existing functions over multiple turns. CodeFlowBench comprises two complementary components: CodeFlowBench-Comp, a core collection of 5,000+ competitive programming problems from Codeforces updated via an automated pipeline and CodeFlowBench-Repo, which is sourced from GitHub repositories to better reflect real-world scenarios. Furthermore, a novel evaluation framework featured dual assessment protocol and structural metrics derived from dependency trees is introduced. Extensive experiments reveal significant performance degradation in multi-turn codeflow scenarios. Furthermore, our in-depth analysis illustrates that model performance inversely correlates with dependency complexity. These findings not only highlight the critical challenges for supporting real-world workflows, but also establish CodeFlowBench as an essential tool for advancing code generation research.