We investigate fairness dynamics during Large Language Model (LLM) training to enable the diagnoses of biases and mitigations through training interventions like early stopping; we find that biases can emerge suddenly and do not always follow common performance metrics. We introduce two new metrics to evaluate fairness dynamics holistically during model pre-training: Average Rank and Jensen-Shannon Divergence by Parts. These metrics provide insights into the Pythia models' progression of biases in gender prediction of occupations on the WinoBias dataset. By monitoring these dynamics, we find that (1) Pythia-6.9b is biased towards men; it becomes more performant and confident predicting "male" than "female" during training, (2) via early-stopping, Pythia-6.9b can exchange 1.7% accuracy on LAMBADA for a 92.5% increase in fairness, and (3) larger models can exhibit more bias; Pythia-6.9b makes more assumptions about gender than Pythia-160m, even when a subject's gender is not specified.