Emotion classification in multilingual settings remains constrained by the scarcity of annotated data: existing corpora are predominantly English, single-label, and cover few languages. We address this gap by constructing a large-scale synthetic training corpus of over 1M multi-label samples (50k per language) across 23 languages: Arabic, Bengali, Dutch, English, French, German, Hindi, Indonesian, Italian, Japanese, Korean, Mandarin, Polish, Portuguese, Punjabi, Russian, Spanish, Swahili, Tamil, Turkish, Ukrainian, Urdu, and Vietnamese, covering 11 emotion categories using culturally-adapted generation and programmatic quality filtering. We train and compare six multilingual transformer encoders, from DistilBERT (135M parameters) to XLM-R-Large (560M parameters), under identical conditions. On our in-domain test set, XLM-R-Large achieves 0.868 F1-micro and 0.987 AUC-micro. To validate against human-annotated data, we evaluate all models zero-shot on GoEmotions (English) and SemEval-2018 Task 1 E-c (English, Arabic, Spanish). On threshold-free ranking metrics, XLM-R-Large matches or exceeds English-only specialist models, tying on AP-micro (0.636) and LRAP (0.804) while surpassing on AUC-micro (0.810 vs. 0.787), while natively supporting all 23 languages. The best base-sized model is publicly available at https://huggingface.co/tabularisai/multilingual-emotion-classification