Academic paper review is a critical yet time-consuming task within the research community. With the increasing volume of academic publications, automating the review process has become a significant challenge. The primary issue lies in generating comprehensive, accurate, and reasoning-consistent review comments that align with human reviewers' judgments. In this paper, we address this challenge by proposing ReviewAgents, a framework that leverages large language models (LLMs) to generate academic paper reviews. We first introduce a novel dataset, Review-CoT, consisting of 142k review comments, designed for training LLM agents. This dataset emulates the structured reasoning process of human reviewers-summarizing the paper, referencing relevant works, identifying strengths and weaknesses, and generating a review conclusion. Building upon this, we train LLM reviewer agents capable of structured reasoning using a relevant-paper-aware training method. Furthermore, we construct ReviewAgents, a multi-role, multi-LLM agent review framework, to enhance the review comment generation process. Additionally, we propose ReviewBench, a benchmark for evaluating the review comments generated by LLMs. Our experimental results on ReviewBench demonstrate that while existing LLMs exhibit a certain degree of potential for automating the review process, there remains a gap when compared to human-generated reviews. Moreover, our ReviewAgents framework further narrows this gap, outperforming advanced LLMs in generating review comments.