Effective management of Service Function Chains (SFCs) and optimal Virtual Network Function (VNF) placement are critical challenges in modern Software-Defined Networking (SDN) and Network Function Virtualization (NFV) environments. Although Deep Reinforcement Learning (DRL) is widely adopted for dynamic network decision-making, its inherent dependency on structured data and fixed action rules often limits adaptability and responsiveness, particularly under unpredictable network conditions. This paper introduces LiLM-RDB-SFC, a novel approach combining Lightweight Language Model (LiLM) with Relational Database (RDB) to answer network state queries to guide DRL model for efficient SFC provisioning. Our proposed approach leverages two LiLMs, Bidirectional and Auto-Regressive Transformers (BART) and the Fine-tuned Language Net T5 (FLAN-T5), to interpret network data and support diverse query types related to SFC demands, data center resources, and VNF availability. Results demonstrate that FLAN-T5 outperforms BART with a lower test loss (0.00161 compared to 0.00734), higher accuracy (94.79% compared to 80.2%), and less processing time (2h 2min compared to 2h 38min). Moreover, when compared to the large language model SQLCoder, FLAN-T5 matches the accuracy of SQLCoder while cutting processing time by 96% (SQLCoder: 54 h 43 min; FLAN-T5: 2 h 2 min).