Multilingual Alignment is an effective and representative paradigm to enhance LLMs' multilingual capabilities, which transfers the capabilities from the high-resource languages to the low-resource languages. Meanwhile, some research on language-specific neurons provides a new perspective to analyze and understand LLMs' mechanisms. However, we find that there are many neurons that are shared by multiple but not all languages and cannot be correctly classified. In this work, we propose a ternary classification methodology that categorizes neurons into three types, including language-specific neurons, language-related neurons, and general neurons. And we propose a corresponding identification algorithm to distinguish these different types of neurons. Furthermore, based on the distributional characteristics of different types of neurons, we divide the LLMs' internal process for multilingual inference into four parts: (1) multilingual understanding, (2) shared semantic space reasoning, (3) multilingual output space transformation, and (4) vocabulary space outputting. Additionally, we systematically analyze the models before and after alignment with a focus on different types of neurons. We also analyze the phenomenon of "Spontaneous Multilingual Alignment". Overall, our work conducts a comprehensive investigation based on different types of neurons, providing empirical results and valuable insights to better understand multilingual alignment and multilingual capabilities of LLMs.