As large language models (LLMs) gain popularity, their vulnerability to adversarial attacks emerges as a primary concern. While fine-tuning models on domain-specific datasets is often employed to improve model performance, it can inadvertently introduce vulnerabilities within the underlying model. In this work, we investigate Accidental Vulnerability, unexpected vulnerabilities arising from characteristics of fine-tuning data. We begin by identifying potential correlation factors such as linguistic features, semantic similarity, and toxicity across multiple experimental datasets. We then evaluate the adversarial robustness of these fine-tuned models, analyzing persona shifts and interpretability traits to understand how dataset factors contribute to attack success rates. Lastly, we explore causal relationships that offer new insights into adversarial defense strategies, highlighting the crucial role of dataset design in preserving model alignment. Our code is available at https://github.com/psyonp/accidental_vulnerability.