To enhance LLMs' impact on math education, we need data on their mathematical prowess and biases across prompts. To fill this gap, we introduce MEDS (Math Education Digital Shadows) as a dataset mapping how large language models reason about and report mathematics across human- and AI-like conditions. MEDS involves 28,000 personas from 14 LLMs (from families like Mistral, Qwen, DeepSeek, Granite, Phi and Grok) shadowing either humans or AI assistants. Each record/shadow includes a set of prompts along with psychological/sociodemographic persona metadata and four types of math tasks: (i) open math interview, (ii) three psychometric tests about math perceptions with explanations, (iii) cognitive networks capturing math attitudes, and (iv) 18 high-school math test questions together with their reasoning and confidence scores. MEDS differs from traditional score-only math benchmarks because it integrates concepts of self-efficacy, math anxiety, and cognitive network science besides math proficiency scores. Data validation shows that the sampled LLMs exhibit schema integrity and consistent personas, together with family-specific peculiarities like human-like negative math attitudes, logical fallacies, and math overconfidence. MEDS will benefit learning analytics experts, cognitive scientists, and developers of safer AI tutors in mathematics.