The integration of Digital Twins with Extended Reality technologies, such as Virtual Reality and Augmented Reality, is transforming industries by enabling more immersive, interactive experiences and enhancing real time decision making. User centered evaluations are crucial for aligning XR enhanced DT systems with user expectations, enhancing acceptance and utility in real world settings. This paper proposes a user centric evaluation method for XR enhanced DT applications to assess usability, cognitive load, and user experience. By employing a range of assessment tools, including questionnaires and observational studies across various use cases, such as virtual tourism, city planning, and industrial maintenance, this method provides a structured approach to capturing the users perspective.