Integrating large language models (LLMs) like ChatGPT into computer science education offers transformative potential for complex courses such as data structures and algorithms (DSA). This study examines ChatGPT as a supplementary tool for teaching assistants (TAs), guided by structured prompts and human oversight, to enhance instruction and student outcomes. A controlled experiment compared traditional TA-led instruction with a hybrid approach where TAs used ChatGPT-4o and ChatGPT o1 to generate exercises, clarify concepts, and provide feedback. Structured prompts emphasized problem decomposition, real-world context, and code examples, enabling tailored support while mitigating over-reliance on AI. Results demonstrated the hybrid approach's efficacy, with students in the ChatGPT-assisted group scoring 16.50 points higher on average and excelling in advanced topics. However, ChatGPT's limitations necessitated TA verification. This framework highlights the dual role of LLMs: augmenting TA efficiency while ensuring accuracy through human oversight, offering a scalable solution for human-AI collaboration in education.