Integrating expressive generative policies, such as flow-matching models, into offline reinforcement learning (RL) allows agents to capture complex, multi-modal behaviors. While Q-learning with Adjoint Matching (QAM) stabilizes policy optimization via the continuous adjoint method, it remains inherently bound to the fixed behavior distribution. This dependence induces a \textit{popularity bias} that can suppress high-reward actions in low-density regions, and creates a \textit{support binding} that restricts off-manifold exploration. Existing workarounds, such as appending \textit{residual} Gaussian policies, often re-introduce the expressivity bottlenecks associated with unimodal distributions. In this work, we propose \textit{Maximum Entropy Adjoint Matching} (ME-AM), a unified framework that addresses these limitations within the continuous flow formulation. ME-AM incorporates two mechanisms: (1) a Mirror Descent entropy maximization objective that mitigates the popularity bias to facilitate the extraction of optimal policies from offline datasets, and (2) a \textit{Mixture Behavior Prior} that broadens the geometric support to encompass out-of-distribution high-reward regions. By exploring this extended geometry, ME-AM identifies robust actions while preserving the absolute continuity of the generative vector field. Empirically, ME-AM demonstrates competitive or superior performance compared to prior state-of-the-art (SOTA) methods across a diverse suite of sparse-reward continuous control environments.