Flow matching as a paradigm of generative model achieves notable success across various domains. However, existing methods use either multi-round training or knowledge within minibatches, posing challenges in finding a favorable coupling strategy for straightening trajectories to few-step generation. To address this issue, we propose a novel approach, Straighter trajectories of Flow Matching (StraightFM). It straightens trajectories with the coupling strategy from the entire distribution level. More specifically, during training, StraightFM creates couplings of images and noise via one diffusion model as a coupling prior to straighten trajectories for few-step generation. Our coupling strategy can also integrate with the existing coupling direction from real data to noise, improving image quality in few-step generation. Experimental results on pixel space and latent space show that StraightFM yields attractive samples within 5 steps. Moreover, our unconditional StraightFM is seamlessly compatible with training-free multimodal conditional generation, maintaining high-quality image generation in few steps.