Advances in artificial intelligence (AI) including foundation models (FMs), are increasingly transforming human society, with smart city driving the evolution of urban living.Meanwhile, vehicle crowdsensing (VCS) has emerged as a key enabler, leveraging vehicles' mobility and sensor-equipped capabilities. In particular, ride-hailing vehicles can effectively facilitate flexible data collection and contribute towards urban intelligence, despite resource limitations. Therefore, this work explores a promising scenario, where edge-assisted vehicles perform joint tasks of order serving and the emerging foundation model fine-tuning using various urban data. However, integrating the VCS AI task with the conventional order serving task is challenging, due to their inconsistent spatio-temporal characteristics: (i) The distributions of ride orders and data point-of-interests (PoIs) may not coincide in geography, both following a priori unknown patterns; (ii) they have distinct forms of temporal effects, i.e., prolonged waiting makes orders become instantly invalid while data with increased staleness gradually reduces its utility for model fine-tuning.To overcome these obstacles, we propose an online framework based on multi-agent reinforcement learning (MARL) with careful augmentation. A new quality-of-service (QoS) metric is designed to characterize and balance the utility of the two joint tasks, under the effects of varying data volumes and staleness. We also integrate graph neural networks (GNNs) with MARL to enhance state representations, capturing graph-structured, time-varying dependencies among vehicles and across locations. Extensive experiments on our testbed simulator, utilizing various real-world foundation model fine-tuning tasks and the New York City Taxi ride order dataset, demonstrate the advantage of our proposed method.