In the field of financial derivatives trading, managing volatility risk is crucial for protecting investment portfolios from market changes. Traditional Vega hedging strategies, which often rely on basic and rule-based models, are hard to adapt well to rapidly changing market conditions. We introduce a new framework for dynamic Vega hedging, the Adaptive Nesterov Accelerated Distributional Deep Hedging (ANADDH), which combines distributional reinforcement learning with a tailored design based on adaptive Nesterov acceleration. This approach improves the learning process in complex financial environments by modeling the hedging efficiency distribution, providing a more accurate and responsive hedging strategy. The design of adaptive Nesterov acceleration refines gradient momentum adjustments, significantly enhancing the stability and speed of convergence of the model. Through empirical analysis and comparisons, our method demonstrates substantial performance gains over existing hedging techniques. Our results confirm that this innovative combination of distributional reinforcement learning with the proposed optimization techniques improves financial risk management and highlights the practical benefits of implementing advanced neural network architectures in the finance sector.