General-purpose large language models (LLMs) are increasingly deployed in verticals such as telecommunications, where adaptation is hindered by scarce, low-information-density corpora and tight mobile/edge constraints. We propose Data Trajectory Alignment (DTA), a two-phase, model-agnostic data curation framework that treats solution processes - not only final answers - as first-class supervision. Phase I (Initializing) synthesizes diverse, high-coverage candidates using an ensemble of strong teachers. Phase II (DTA) rewrites teacher solutions to align intermediate steps and presentation style with the target student's inductive biases and then performs signal-aware exemplar selection via agreement checks and reflection-based judging. Instantiated on telecommunications mathematics (e.g., link budgets, SNR/AMC selection, and power-control feasibility), DTA yields state-of-the-art (SOTA) accuracy on TELEMATH without enabling explicit "thinking" modes: 72.45% pass@1, surpassing distilled-only training by +17.65 points and outperforming a strong baseline (Qwen3-32B with thinking enabled) by +2.94 points. Token-shift analyses indicate that DTA concentrates gains on logical-structural discourse markers rather than merely amplifying domain nouns, indicating improved reasoning scaffolding. Under edge-like inference settings, DTA improves efficiency by reducing reliance on multi-sample voting and disabling expensive reasoning heuristics, cutting energy per output token by ~42% versus Qwen3-32B (thinking mode enabled) and end-to-end latency by ~60% versus Qwen3-32B (thinking mode disabled). These results demonstrate that aligning how solutions are produced enables compact, high-yield supervision that is effective for both accuracy and efficiency, offering a practical recipe for domain adaptation in low-resource verticals beyond telecom.