As the density of spacecraft in Earth's orbit increases, their recognition, pose and trajectory identification becomes crucial for averting potential collisions and executing debris removal operations. However, training models able to identify a spacecraft and its pose presents a significant challenge due to a lack of available image data for model training. This paper puts forth an innovative framework for generating realistic synthetic datasets of Resident Space Object (RSO) imagery. Using the International Space Station (ISS) as a test case, it goes on to combine image regression with image restoration methodologies to estimate pose from blurred images. An analysis of the proposed image recovery and regression techniques was undertaken, providing insights into the performance, potential enhancements and limitations when applied to real imagery of RSOs. The image recovery approach investigated involves first applying image deconvolution using an effective point spread function, followed by detail object extraction with a U-Net. Interestingly, using only U-Net for image reconstruction the best pose performance was attained, reducing the average Mean Squared Error in image recovery by 97.28% and the average angular error by 71.9%. The successful application of U-Net image restoration combined with the Resnet50 regression network for pose estimation of the International Space Station demonstrates the value of a diverse set of evaluation tools for effective solutions to real-world problems such as the analysis of distant objects in Earth's orbit.