The rapid growth of Electric Vehicle (EV) adoption challenges power distribution networks through peak load spikes, voltage instability, and transformer overloads from uncoordinated charging. While Model Predictive Control (MPC) and standard Reinforcement Learning (RL) methods have addressed these issues, existing approaches rarely treat real-time carbon intensity or fluctuating renewable energy (RE) availability as primary scheduling objectives, leaving substantial decarbonisation potential unrealised. This paper proposes an emission-aware RL strategy based on the Soft Actor Critic (SAC) algorithm, with a multi-objective reward that penalises carbon emissions, curtailed on-site renewables, and unmet user demand. The agent is trained within a unified benchmarking framework on the EV2Gym platform, incorporating behind-the-meter solar and wind profiles, time-varying EirGrid carbon intensity data, and realistic workplace EV behaviour across 25 Electric Vehicle Supply Equipment (EVSE) units. Nine control strategies, including heuristics, emission-aware MPC variants, and the proposed RL agent, are compared under five renewable penetration scenarios (0%-50%) over ten independent runs each. The RL agent achieves a carbon intensity as low as 23.96 grams of carbon dioxide per kilowatt-hour under 50% wind penetration, representing up to 87% emission reduction versus the uncontrolled baseline, and outperforms the external graph-based Power Distribution Network (PDN) benchmark. Transformer overload remains below 7 kWh across scenarios, against up to 1093 kWh for the As Fast As Possible (AFAP) heuristic, and renewable self-consumption reaches 52% under combined wind and solar supply. Embedding carbon intensity forecasts into the RL state and reward aligns charging with low-emission periods while preserving grid compliance and user satisfaction.