The automated and intelligent processing of massive remote sensing (RS) datasets is critical in Earth observation (EO). Existing automated systems are normally task-specific, lacking a unified framework to manage diverse, end-to-end workflows--from data preprocessing to advanced interpretation--across diverse RS applications. To address this gap, this paper introduces CangLing-KnowFlow, a unified intelligent agent framework that integrates a Procedural Knowledge Base (PKB), Dynamic Workflow Adjustment, and an Evolutionary Memory Module. The PKB, comprising 1,008 expert-validated workflow cases across 162 practical RS tasks, guides planning and substantially reduces hallucinations common in general-purpose agents. During runtime failures, the Dynamic Workflow Adjustment autonomously diagnoses and replans recovery strategies, while the Evolutionary Memory Module continuously learns from these events, iteratively enhancing the agent's knowledge and performance. This synergy enables CangLing-KnowFlow to adapt, learn, and operate reliably across diverse, complex tasks. We evaluated CangLing-KnowFlow on the KnowFlow-Bench, a novel benchmark of 324 workflows inspired by real-world applications, testing its performance across 13 top Large Language Model (LLM) backbones, from open-source to commercial. Across all complex tasks, CangLing-KnowFlow surpassed the Reflexion baseline by at least 4% in Task Success Rate. As the first most comprehensive validation along this emerging field, this research demonstrates the great potential of CangLing-KnowFlow as a robust, efficient, and scalable automated solution for complex EO challenges by leveraging expert knowledge (Knowledge) into adaptive and verifiable procedures (Flow).