Compilation errors pose pervasive and critical challenges in software development, significantly hindering productivity. Therefore, Automated Compilation Error Repair (ACER) techniques are proposed to mitigate these issues. Despite recent advancements in ACER, its real-world performance remains poorly evaluated. This can be largely attributed to the limitations of existing benchmarks, \ie decontextualized single-file data, lack of authentic source diversity, and biased local task modeling that ignores crucial repository-level complexities. To bridge this critical gap, we propose ComBench, the first repository-level, reproducible real-world benchmark for C/C++ compilation error repair. ComBench is constructed through a novel, automated framework that systematically mines real-world failures from the GitHub CI histories of large-scale open-source projects. Our framework contributes techniques for the high-precision identification of ground-truth repair patches from complex version histories and a high-fidelity mechanism for reproducing the original, ephemeral build environments. To ensure data quality, all samples in ComBench are execution-verified -- guaranteeing reproducible failures and build success with ground-truth patches. Using ComBench, we conduct a comprehensive evaluation of 12 modern LLMs under both direct and agent-based repair settings. Our experiments reveal a significant gap between a model's ability to achieve syntactic correctness (a 73% success rate for GPT-5) and its ability to ensure semantic correctness (only 41% of its patches are valid). We also find that different models exhibit distinct specializations for different error types. ComBench provides a robust and realistic platform to guide the future development of ACER techniques capable of addressing the complexities of modern software development.