Electronic nose (E-nose) systems face two interconnected challenges in open-set gas recognition: feature distribution shift caused by signal drift and decision boundary failure induced by unknown gas interference. Existing methods predominantly rely on Euclidean distance or conventional classifiers, failing to account for anisotropic feature distributions and dynamic signal intensity variations. To address these issues, this study proposes the Spherical Normalization coupled Mahalanobis (SNM) module, a universal post-processing module for open-set gas recognition. First, it achieves geometric decoupling through cascaded batch and L2 normalization, projecting features onto a unit hypersphere to eliminate signal intensity fluctuations. Second, it utilizes Mahalanobis distance to construct adaptive ellipsoidal decision boundaries that conform to the anisotropic feature geometry. The architecture-agnostic SNM-Module seamlessly integrates with mainstream backbones including Convolutional Neural Network (CNN), Recurrent Neural Network (RNN), and Transformer. Experiments on the public Vergara dataset demonstrate that the Transformer+SNM configuration achieves near-theoretical-limit performance in discriminating among multiple target gases, with an AUROC of 0.9977 and an unknown gas detection rate of 99.57% at 5% false positive rate, significantly outperforming state-of-the-art methods with a 3.0% AUROC improvement and 91.0% standard deviation reduction compared to Class Anchor Clustering (CAC). The module maintains exceptional robustness across five sensor positions, with standard deviations below 0.0028. This work effectively addresses the critical challenge of simultaneously achieving high accuracy and high stability in open-set gas recognition, providing solid support for industrial E-nose deployment.