The quality of process data plays a key role in training a Process Reward Model (PRM), which can enhance the complex mathematical reasoning capability of large language models. Existing methods estimate the quality of reasoning steps based on a fixed-budget sampling strategy and navigate a vast search space to perform path expansion during the automated data generation process, resulting in their inefficiency and inflexibility. To address these issues, we propose Adaptive Monte Carlo Search (AMCS), a framework that transforms data generation from fixed, static to adaptive, dynamic search at the level of node value estimation and path expansion. On one hand, AMCS adaptively refines estimation by allocating more samples to uncertain reasoning steps while using fewer samples for those that are easier to estimate. On the other hand, it enhances the path expansion through a Monte Carlo algorithm with a temporally adaptive policy that begins with broad exploration and gradually shifts toward exploiting the most promising directions. With AMCS, we construct a large-scale dataset MathSearch-200K of about 200K process supervision examples for training PRMs. To verify the effectiveness of our method, we conduct extensive experiments on four mathematical reasoning benchmarks. Experimental results show that Qwen2.5-Math-7B-PRM-AMCS achieves up to 76.2% accuracy on MATH500 with GLM-4-9B, outperforming all baseline PRMs. Notably, a 7B model supervised by Qwen2.5-Math-7B-PRM-AMCS surpasses a 72B model with weaker supervision. Moreover, Qwen2.5-Math-7B-PRM-AMCS maintains consistent advantages on out-of-distribution problems, demonstrating strong generalization capability. Our code is available at https://github.com/reml-group/AMCS.