For stabilizing control tasks, model-free reinforcement learning (RL) approaches face numerous challenges, particularly regarding the issues of effectiveness and efficiency in complex high-dimensional environments with limited training data. To address these challenges, we propose Multi-Step Actor-Critic Learning with Lyapunov Certificates (MSACL), a novel approach that integrates exponential stability into off-policy maximum entropy reinforcement learning (MERL). In contrast to existing RL-based approaches that depend on elaborate reward engineering and single-step constraints, MSACL adopts intuitive reward design and exploits multi-step samples to enable exploratory actor-critic learning. Specifically, we first introduce Exponential Stability Labels (ESLs) to categorize training samples and propose a $λ$-weighted aggregation mechanism to learn Lyapunov certificates. Based on these certificates, we further design a stability-aware advantage function to guide policy optimization, thereby promoting rapid Lyapunov descent and robust state convergence. We evaluate MSACL across six benchmarks, comprising four stabilizing and two high-dimensional tracking tasks. Experimental results demonstrate its consistent performance improvements over both standard RL baselines and state-of-the-art Lyapunov-based RL algorithms. Beyond rapid convergence, MSACL exhibits robustness against environmental uncertainties and generalization to unseen reference signals. The source code and benchmarking environments are available at \href{https://github.com/YuanZhe-Xing/MSACL}{https://github.com/YuanZhe-Xing/MSACL}.