This paper investigates a multi-Unmanned Aerial Vehicle (UAV) joint base station-assisted Internet of Vehicles (IoV) task offloading system in dense urban environments. To minimize system delay and energy consumption under strict coupling constraints, the complex non-convex optimization problem is decoupled into a hierarchical execution framework. First, a sequential distributed optimization algorithm based on Second-Order Cone Programming (SOCP) is proposed to optimize the 3D flight trajectory of each UAV, ensuring adaptive network coverage. Second, a novel hybrid resource scheduling paradigm synergizing Deep Reinforcement Learning (DRL) and Large Language Models (LLMs) is developed. Within this framework, the DRL agent dictates the initial resource allocation, while the LLM acts as a semantic macro-scheduler to rectify long-tail allocation imbalances for failed and surplus tasks. Crucially, a reward decoupling mechanism is introduced to isolate DRL training from external LLM interventions, thereby ensuring policy convergence. Finally, the task offloading ratios are precisely determined via Linear Programming (LP) within an alternating optimization loop. Simulation results demonstrate that the proposed method significantly outperforms traditional multi-agent reinforcement learning baselines in terms of task success rate and system efficiency.