Large Language Models can generate synthetic survey responses at low cost, but their accuracy varies unpredictably across questions. We study the design problem of allocating a fixed budget of human respondents across estimation tasks when cheap LLM predictions are available for every task. Our framework combines three components. First, building on Prediction-Powered Inference, we characterize a question-specific rectification difficulty that governs how quickly the estimator's variance decreases with human sample size. Second, we derive a closed-form optimal allocation rule that directs more human labels to tasks where the LLM is least reliable. Third, since rectification difficulty depends on unobserved human responses for new surveys, we propose a meta-learning approach, trained on historical data, that predicts it for entirely new tasks without pilot data. The framework extends to general M-estimation, covering regression coefficients and multinomial logit partworths for conjoint analysis. We validate the framework on two datasets spanning different domains, question types, and LLMs, showing that our approach captures 61-79% of the theoretically attainable efficiency gains, achieving 11.4% and 10.5% MSE reductions without requiring any pilot human data for the target survey.