As atmospheric environmental prediction continues to improve, interpretable validation of pollution mechanisms and feedback processes has become a main challenge in atmospheric chemistry. Yet mechanism validation based on complex numerical models still relies heavily on expert knowledge: mechanistic hypotheses must be operationalized into executable experiments, and model outputs must be organized into traceable evidence. We present TianJi-Environ, an auditable AI Scientist for atmospheric-chemistry mechanism validation. TianJi-Environ establishes the first WRF-Chem-based multi-agent framework that autonomously drives complex atmospheric-chemistry simulations, converting mechanistic hypotheses into executable configurations, testing experiments, and evidence criteria. Using ozone response and particulate-matter feedback as two representative examples, we demonstrate TianJi-Environ's capability for mechanism validation. In a summertime ozone case over the North China Plain, the system detects directionally consistent aerosol-radiation-interaction signals in shortwave radiation and boundary-layer height, but judges the evidence for ozone response to NOx control to be incomplete. In a wintertime PM2.5 case over the Guanzhong Basin, it localizes the unsupported link to insufficient propagation from black-carbon perturbation to particulate response and missing diagnostics of vertical absorptive heating. These results show that TianJi-Environ makes expert-driven mechanism validation explicit, structured, and auditable, offering a reproducible paradigm for multi-agent systems coupled with complex atmospheric-chemistry models.