The optimal power flow (OPF) is a multi-valued, non-convex mapping from loads to dispatch setpoints. The variability of system parameters (e.g., admittances, topology) further contributes to the multiplicity of dispatch setpoints for a given load. Existing deep learning OPF solvers are single-valued and thus fail to capture the variability of system parameters unless fully represented in the feature space, which is prohibitive. To solve this problem, we introduce a diffusion-based OPF solver, termed \textit{DiffOPF}, that treats OPF as a conditional sampling problem. The solver learns the joint distribution of loads and dispatch setpoints from operational history, and returns the marginal dispatch distributions conditioned on loads. Unlike single-valued solvers, DiffOPF enables sampling statistically credible warm starts with favorable cost and constraint satisfaction trade-offs. We explore the sample complexity of DiffOPF to ensure the OPF solution within a prescribed distance from the optimization-based solution, and verify this experimentally on power system benchmarks.