Large Language Models (LLMs) are increasingly relied upon for complex workflows, yet their ability to maintain flow of instructions remains underexplored. Existing benchmarks conflate task complexity with structural ordering, making it difficult to isolate the impact of prompt topology on performance. We introduce RIFT, Reordered Instruction Following Testbed, to assess instruction following by disentangling structure from content. Using rephrased Jeopardy! question-answer pairs, we test LLMs across two prompt structures: linear prompts, which progress sequentially, and jumping prompts, which preserve identical content but require non-sequential traversal. Across 10,000 evaluations spanning six state-of-the-art open-source LLMs, accuracy dropped by up to 72% under jumping conditions (compared to baseline), revealing a strong dependence on positional continuity. Error analysis shows that approximately 50% of failures stem from instruction-order violations and semantic drift, indicating that current architectures internalize instruction following as a sequential pattern rather than a reasoning skill. These results reveal structural sensitivity as a fundamental limitation in current architectures, with direct implications for applications requiring non-sequential control flow such as workflow automation and multi-agent systems.