Reasoning language models deployed in agentic workflows must follow an instruction hierarchy: when instructions from different sources conflict, the model should obey the highest-privilege applicable instruction. Existing benchmarks largely measure this behavior end-to-end, asking whether the final response is compliant. However, a non-compliant response can arise from several distinct failures: the model may fail to identify the relevant instructions in context, fail to resolve conflicts among identified instructions, or correctly resolve the conflict in its reasoning while still producing a violating response. We introduce a white-box diagnostic framework that localizes instruction hierarchy failures into instruction identification, conflict resolution, and response realization, making failures more interpretable. We evaluate three reasoning models--Gemma-4-31B-IT, Qwen3.6-35B-A3B, and Claude Sonnet 4.6--on long-context adaptations of IHEval and IHChallenge, and find that the dominant failure mode varies across models, tasks, and context length. Building on the observation that models can often detect conflicts and output violations when explicitly prompted, we propose two training-free self-monitoring mechanisms: a parallel input monitor for low-latency conflict detection before generation, and a sequential output monitor for response-level review and repair. Across Gemma-4-31B-IT, Claude Sonnet 4.6, and GPT-5.3, the strongest monitor reduces rule-following non-compliance by 81-99%, with GPT-5.3 reductions of 86% under static attacks and 45% under adaptive attacks.