We continue the study of real polynomials acting entrywise on matrices of fixed dimension to preserve positive semidefiniteness, together with the related analysis of order properties of Schur polynomials. Previous work has shown that, given a real polynomial with positive coefficients that is perturbed by adding a higher-degree monomial, there exists a negative lower bound for the coefficient of the perturbation which characterizes when the perturbed polynomial remains positivity preserving. We show here that, if the perturbation coefficient is strictly greater than this bound then the transformed matrix becomes positive definite given a simple genericity condition that can be readily verified. We identity a slightly stronger genericity condition that ensures positive definiteness occurs at the boundary. The analysis is complemented by computing the rank of the transformed matrix in terms of the location of the original matrix in a Schubert cell-type stratification that we have introduced and explored previously. The proofs require enhancing to strictness a Schur monotonicity result of Khare and Tao, to show that the ratio of Schur polynomials is strictly increasing along each coordinate on the positive orthant and non-decreasing on its closure whenever the defining tuples satisfy a coordinate-wise domination condition.