Tuning parameter selection is of critical importance for kernel ridge regression. To this date, data driven tuning method for divide-and-conquer kernel ridge regression (d-KRR) has been lacking in the literature, which limits the applicability of d-KRR for large data sets. In this paper, by modifying the Generalized Cross-validation (GCV, Wahba, 1990) score, we propose a distributed Generalized Cross-Validation (dGCV) as a data-driven tool for selecting the tuning parameters in d-KRR. Not only the proposed dGCV is computationally scalable for massive data sets, it is also shown, under mild conditions, to be asymptotically optimal in the sense that minimizing the dGCV score is equivalent to minimizing the true global conditional empirical loss of the averaged function estimator, extending the existing optimality results of GCV to the divide-and-conquer framework.